Infrared spectra and structures of C60Rhn+ complexes

نویسندگان

چکیده

Metal clusters supported on carbonaceous substrates are of interest in catalysis, hydrogen storage, and other fields. In this paper, the structures infrared spectra C60Rhn+ (n = 1–6) fullerene-metal complexes studied by a combination mass-selective spectroscopy theoretical calculations. It is found that clustering Rh surface fullerene preferred over wetting. For Rh4+ Rh6+, adsorbed different from those free clusters. There electron transfer metal cluster to neutral C60Rhn, cationic deficit shared fullerene. Adsorption Rhn leads degeneracy lifting most intense C60 features were measured 300–850 cm−1 range. Agreement obtained, general, between experimental D2-tagged calculated for untagged C60Rhn+, except 600–750 region, where mainly arise presence D2-messenger molecules

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ژورنال

عنوان ژورنال: Carbon

سال: 2022

ISSN: ['0008-6223', '1873-3891']

DOI: https://doi.org/10.1016/j.carbon.2022.07.002